Aquat. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been . ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup? ~!W;H"?|6,p /eNYS-IyW{'Bg4{gZ9q/=S6dN|L7}K4>88 7!_?.I*7w7"-g5H?~p~GmYS}wRz}{2O~d:>/.mH$k;A}=E-n0Eq!L2xscD|.3nj xntluww#!4l D3 B!w m lc!7C,_ 1|}6>,74$$dA o K ?i_y[bN#[+O:^1\J+n]kqy.suP8:e8[aKTFXiJUk:u9VQ. All except cyclopenta [ a ]phenanthrene have the numbering explicitly depicted (in P-25.1.1 or P-25.2.1; anthracene and phenanthrene in errata). "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{E0k^|m$}Hx=:l3iB;:>1-E3F: Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Application. Animal studies have shown that phenanthrene is a potential carcinogen. ; Sheldrake, C.P. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.26 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 300 C; End time: 20 min; Start time: 4 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Rostad, C.E. Anthracene can be tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in dendrimers with anthracene cores. >> "Application of chelate Compounds in Analytical Chemistry", "Ni(I)Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers", "Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides", https://en.wikipedia.org/w/index.php?title=1,10-Phenanthroline&oldid=1142107804, Chemical articles with multiple compound IDs, Chemical articles with multiple CAS registry numbers, Chemical articles with multiple PubChem CIDs, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, mild neurotoxin, strong nephrotoxin, and powerful diuretic, This page was last edited on 28 February 2023, at 15:07. Effect and localization of phenanthrene in maize roots. Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . Buying Leads | I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Biological monitoring of exposure to polycyclic aromatic hydrocarbons by determination of unmetabolized compounds in urine. % Disclaimer. Chromatogr. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. and g.c.-m.s. XXXIV. [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. The site is secure. ; Ding, S.F. ; Zhao, C.-X. ; Fang H.Z. Biologically Active Compounds | Packaging 25, 100, 500 g in poly bottle 10, 25 kg Safety Information Pictograms GHS07,GHS09 Signal Word Warning Hazard Statements H302 - H410 Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. stream } !1AQa"q2#BR$3br Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. government site. & Chromatogr. Language links are at the top of the page across from the title. c. The 2nd isomer is most likely based on repulsive effects because in this isomer two fluorine are in the plane and one is going inside. official website and that any information you provide is encrypted ; Kerr, A.A.; Lockington, J.N. It's natural and expected that there can be different numberings for . 2014-09-30T09:58:39.238reyarbro 2018 Jun;237:858-867. Chromatogr., 322, 1985, 71-81. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 100 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. /MediaBox [0 0 612 792] It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. 162 (2-3): 132-138, 2006. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. '. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. Organic Compound; Aromatic Hydrocarbon; Industrial By-product/Pollutant; Polycyclic Aromatic Hydrocarbon; Pollutant; Food Toxin; Industrial/Workplace Toxin; Natural Compound, ORL-MUS LD50 700 mg kg-1, IPR-MUS LD50 700 mg kg-1, IVN-MUS LD50 56 mg kg-1, Harmful/Irritant/Light Sensitive/Store under Argon, Toxic to aquatic life/Harmful/Irritant/Light Sensitive/Store under Argon, WARNING: Irritates skin and eyes, harmful if swallowed, A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene. XXXIV. [3] Soluble in Ether,Benzene,Chloroform,Toluene. $4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C 14 H 10, consisting of three fused benzene rings. L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection. <> The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. [3], Phenanthrene occurs naturally and also is a man-made chemical. The alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline (ca. PMC 1,10-Phenanthroline targets mainly zinc metallopeptidases, with a much lower affinity for calcium. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. Symmetry point group: C 2v: Symmetry elements E C 2 (z) &sigma v (xz) &sigma v (yz) Irriducible representation &Gamma 3N: 24 A 1 + 12 A 2 + 24 B 1 + 12 B 2: Irriducible representation &Gamma vib: 23 A 1 + 11 A 2 + 22 B 1 + 10 B 2: << It has also been used to make bile acids, cholesterol and steroids. Dupuy J, et al. !t^ { 1mJm X>8c_""xpo! Articles of (2H10)Phenanthrene are included as well. It is also used in agrochemical and pharmaceutical intermediates. Isotope. Chem., 51(6), 1979, 768-773. ass: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Data type: Normal alkane RI; Authors: Asif, M.; Fazeelat, T., Characterization of aromatic hydrocarbons in Dhurnal oil from Northen Indus Basin, J. Chem. Phenanthrene: Index: General properties. More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. Markush Group. Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. ; Huang L.F.; Guo F.Q., Comparative analysis of chemical components of essential oils from different samples of Rhododendron with the help of chemometrics methods, Chemom. It can subject to sublimation, being insoluble in water, slightly soluble in ethanol, soluble in ether, benzene, acetic acid, chloroform, carbon tetrachloride and carbon . XVI. A, 774, 1997, 321-332. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 16.6 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. ; Kim, J.-S., Comparison of volatile components in dried scallops (Chlamys farreri and Patinopecten yessoensis) prepared by boiling and steaming methods, J. Agric. endstream ; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. else if(/_Canvas3D/.test(t)){t='WebGL';} Bethesda, MD 20894, Web Policies Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. It is a white solid that is soluble in organic solvents. FOIA ; Dalluge, J.; Brinkman, U.A.Th., Gas chromatography-time-of-flight mass spectrometry for sensitive determination of organic microcontaminants, J. Microcolumn Sep., 11(9), 1999, 663-675. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 35 C; End T: 250 C; Start time: 3 min; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. A low-polarity ( SE-30 ) capillary column, J 1,10-phenanthroline ( phen ) is a man-made chemical the phytochemistry pharmacology. 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